Herman Schultz (Earth-4678)

Herman Schultz, also known as the Shocker, is one of the many villains that Spider-Man fought on his career as the masked vigilante. He used to be a bank robber, having faced the webhead several times, until he was finally arrested, being released on parole some time later. During one of their first battles it resulted in Spider-Man becoming infamous within the Daily Bugle for their destructive battle that severely damaged the Flatiron Building. Spider-Man’s battle with Schultz did teach Peter the importance to avoid a fight that could put civilians in danger.

Source

 * https://marvels-spider-man.fandom.com/wiki/Shocker